Complexes of CuII, NiII, and CoII with 2-cyano-2-(1-oxyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-2-yl)-1-R-ethylenolates

被引：0
|
作者：
P. A. Petrov
G. V. Romanenko
Yu. G. Shvedenkov
V. N. Ikorskii
V. I. Ovcharenko
V. A. Reznikov
R. Z. Sagdeev
机构：
[1] Siberian Branch of the Russian Academy of Sciences,International Tomography Center
[2] Novosibirsk State University,N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry
[3] Siberian Branch of the Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2004年 / 53卷
关键词：
nitroxide radicals; copper; nickel; cobalt; X-ray diffraction analysis; exchange interactions;
D O I：
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中图分类号：
学科分类号：
摘要：
Copper(ii), nickel(ii), and cobalt(ii) complexes with deprotonated enaminoketone derivatives of 2-imidazoline nitroxide were synthesized. Their crystal structures were established by X-ray diffraction analysis, and their magnetic properties were investigated. All complexes exhibit strong (40—110 cm–1) intramolecular ferromagnetic exchange interactions.
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页码：99 / 108
页数：9
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