Crystal structures of [Hg(N-ethylthiourea)2(CN)2] and [Hg(N-propylthiourea)2(CN)2]

被引：0

作者：

H. Sadaf

S. Ahmad

S. Sharif

I. U. Khan

M. Akkurt

S. W. Ng

M. I. Khan

S. A. Bashir

M. Mufakkar

机构：

[1] University of Engineering and Technology,Department of Chemistry

[2] Government College University,Department of Chemistry

[3] Erciyes University,Department of Physics, Faculty of Arts and Sciences

[4] University of Malaya,Department of Chemistry

[5] International Islamic University,Department of Environmental Sciences

来源：

Journal of Structural Chemistry | 2012年 / 53卷

关键词：

mercury(II) cyanide; -ethylthiourea; -propylthiourea; X-ray structures;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Two mercury(II) cyanide complexes of N-ethylthiourea (Ettu) and N-propylthiourea (Prtu) ligands, [Hg(Ettu)2(CN)2] (1) and [Hg(Prtu)2(CN)2] (2), were prepared and their crystal structures were determined by X-ray crystallography. In both structures, the mercury atom is coordinated to two sulfur atoms of thioureas and two cyanide carbon atoms in a pseudo-tetrahedral mode with the bond angles in the range of 90.52(11)–162.2(3)°. The structures are stabilized by N-H—S, N-H—N, and C-H—N intramolecular and intermolecular hydrogen bonds.

引用

页码：151 / 155

页数：4

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