Synthesis and Characterization of Zn(II) and Cd(II) Complexes with Bisdithiophosphonates

被引：0

作者：

M. Karakus

H. Yilmaz

E. Bulak

机构：

[1] Pamukkale University,Department of Chemistry, Faculty of Arts and Science

[2] Ankara University,Department of Chemistry, Faculty of Science

[3] Bogazici University,Chemistry Department

来源：

Russian Journal of Coordination Chemistry | 2005年 / 31卷

关键词：

Spectroscopy; Ammonium; Zinc; Physical Chemistry; Cadmium;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

2,4-Bis(4-methoxyphenyl)-1,3,2,4-dithiodiphosphetane-2,4-disulfide (Lawesson’s reagent) reacts with stoichiometric equivalent of alkane diols HO(CH2)nOH (n=2, 3, and 5) to form bisdithiophosphonic acid. The obtained crude bisdithiophosphonic acids are treated with dry NH3 to give ammonium salts of bisdithiophosphonic acids. Ammonium salts of bisdithiophosphonic acids react with ZnSO4 in water and Cd(Ac)2 in ethanol to form new bisdithiophosphonate complexes of Zn(II) and Cd(II). The zinc and cadmium complexes of these tetradentate ligands are isolated in high yields. Ammonium salts of bisdithiophosphonic acids and their Zn(II) and Cd(II) complexes are characterized by elemental analyses, mass spectra (ESI), IR and NMR spectroscopies.

引用

页码：316 / 321

页数：5

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