Crystal structures of trans-[Re6S8(CN)2L4] complexes, L = pyridine or 4-methylpyridine

被引：0

作者：

A. Yu. Ledneva

N. G. Naumov

A. V. Virovets

S. Cordier

Y. Molard

机构：

[1] Siberian Division,A. V. Nikolaev Institute of Inorganic Chemistry

[2] Russian Academy of Sciences,undefined

[3] University of Rennes-1,undefined

来源：

Journal of Structural Chemistry | 2012年 / 53卷

关键词：

rhenium; octahedral cluster; crystal structure; stacking interactions; topological packing analysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The structures of three novel octahedral rhenium cluster compounds [Re6S8(CN)2(py)4]·H2O (1), [Re6S8(CN)2(4-Mepy)4] (2), [Re6S8(CN)2(4-Mepy)4]·4-Mepy (3) (py = pyridine, 4-Mepy = 4-methylpyridine) are determined by X-ray crystallography. Crystal data are: C2/m space group, a = 14.813(1) Å, b = 14.772(1) Å, c = 9.2122(6) Å, β = 119.085(2)°, V = 1761.7(2) Å3, dx = 3.318 g/cm3, R = 0.0585 (1); I41/amd space group, a = 16.0018(3) Å, c = 14.7186(5) Å, V = 3768.81(16) Å3, dx = 3.169 g/cm3, R = 0.0489 (2); P21/c space group, a = 9.0452(4) Å, b = 15.8065(7) Å, c = 15.2951(6) Å, β = 103.700(2)°, V = 2124.57(16) Å3, dx = 2.957 g/cm3, R = 0.0245 (3). Molecular cluster complexes interact via π-π stacking affording 3D frameworks in 1 and 2 and chains in 3.

引用

页码：132 / 137

页数：5

共 50 条

[11] CRYSTAL STRUCTURE OF (enH)(enH2)[{Cu2(μ-CN)}Re6S8(CN)6]
A. V. Ermolaev
A. I. Smolentsev
Yu. V. Mironov
Journal of Structural Chemistry, 2021, 62 : 1648 - 1652
[12] Investigation of nitro-nitrito photoisomerization: crystal structures of trans-{2,2 '-[ethane-1,2-diylbis-(nitrilomethylidyne)]diphenolato}(pyridine/4-methylpyridine)nitrocobalt(III)
Ohba, Shigeru
Tsuchimoto, Masanobu
Yamada, Naoki
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1759 - +
[13] STRUCTURAL AND PREPARATIVE STUDIES OF WX4L2(X=CL,BR-L=PYRIDINE,4-METHYLPYRIDINE) AND CRYSTAL-STRUCTURE OF WCI4PY2
BRENCIC, JV
CEH, B
SEGEDIN, P
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1979, 454 (07): : 181 - 186
[14] Controlling the dimensionality in H bonded systems involving octahedral [Re 6 Q 8 (CN) 6 ] 4-and trans-[Re 6 S 8 (CN) 4 (H 2 O) 2 ] 2-anions
Ledneva, A. Yu.
Naumov, N. G.
Kyritsakas, N.
Ferlay, S.
INORGANICA CHIMICA ACTA, 2024, 571
[15] Spectral and electrochemical study of coordination molecules Cu4OX6L4:: 3-methylpyridine and 4-methylpyridine Cu4OBrnCl(6-n)L4 complexes
Ondrejovic, G
Kotocová, A
CHEMICAL PAPERS, 2006, 60 (01) : 10 - 21
[16] In-situ generation of trans-[Ru(pyridine)4(L)(solvent)]2+ obtained by Cl- abstraction from trans-[Ru(pyridine)4(L)(Cl)]+.
Kuber, A
Nandor, H
Hira, S
Petrichko, R
Von Riesen, DD
Timpson, C
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U157 - U158
[17] 23-Electron Re6 metal clusters: syntheses and crystal structures of (Ph4P)3[Re6S8(CN)6], (Ph4P)2(H)[Re6Se8(CN)6]·8H2O, and (Et4N)2(H)[Re6Te8(CN)6]·2H2O
N. G. Naumov
E. V. Ostanina
A. V. Virovets
M. Schmidtman
A. Müller
V. E. Fedorov
Russian Chemical Bulletin, 2002, 51 : 866 - 871
[18] Octahedral cyanohydroxo cluster complex trans-[Re6Se8(CN)4(OH)2]4-: Synthesis, crystal structure, and properties
Mironov, Yuri V.
Brylev, Konstantin A.
Kim, Sung-Jin
Kozlova, Svetlana G.
Kitamura, Noboru
Fedorov, Vladimir E.
INORGANICA CHIMICA ACTA, 2011, 370 (01) : 363 - 368
[19] 23-Electron Re6 metal clusters:: Syntheses and crystal structures of (Ph4P)3[Re6S8(CN)6], (Ph4P)2(H)[Re6Se8(CN)6] • 8H2O, and (Et4N)2(H)[Re6Te8(CN)6] • 2H2O
Naumov, NG
Ostanina, EV
Virovets, AV
Schmidtman, M
Müller, A
Fedorov, VE
RUSSIAN CHEMICAL BULLETIN, 2002, 51 (05) : 866 - 871
[20] The First Octahedral Cluster Complexes With Terminal Formate Ligands: Synthesis, Structure, and Properties of K4[Re6S8(HCOO)6] and Cs4[Re6S8(HCOO)6]
Brylev, Konstantin A.
Mironov, Yuri V.
Kozlova, Svetlana G.
Fedorov, Vladimir E.
Kim, Sung-Jin
Pietzsch, Hans-Juergen
Stephan, Holger
Ito, Akitaka
Ishizaka, Shoji
Kitamura, Noboru
INORGANIC CHEMISTRY, 2009, 48 (05) : 2309 - 2315

← 1 2 3 4 5 →