Building up of Macroring in the New Synthesis of Azacrown Ethers. Structure and Complex Formation of Nitrobenzoazacrown Ethers

被引：0
|
作者：
S. P. Gromov
S. N. Dmitrieva
M. V. Churakova
A. I. Vedernikov
N. A. Kurchavov
L. G. Kuzmina
N. A. Kataeva
J.A. Howard
机构：
[1] Photochemical Center of the Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Russian Academy of Sciences,Chemistry Department
[3] Durham University,undefined
来源：
Russian Journal of Organic Chemistry | 2004年 / 40卷
关键词：
Ether; Organic Chemistry; Titration; Complex Formation; Metal Cation;
D O I：
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中图分类号：
学科分类号：
摘要：
A cyclization of azapodand haloderivatives into nitrobenzoazacrown ethers under treatment with various bases and in their absence was investigated. The nitrobenzoazacrown ethers obtained and their complexes with metal cations were studied by X-ray diffraction method and by 1H NMR titration. In nitrobenzoaza-15-crown-5 a capability to complex Ca2+ cation was found that significantly exceeded similar ability of nitrobenzocrown ether with the same size of the macroring.
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页码：1200 / 1209
页数：9
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