Behavior of Allylamines in the System KOH-DMSO

被引：0
|
作者：
G. K. Musorin
机构：
[1] Russian Academy of Sciences,Favorskii Irkutsk Institute of Chemistry, Siberian Division
来源：
Russian Journal of Organic Chemistry | 2003年 / 39卷
关键词：
Ethyl; Organic Chemistry; Similar Condition; Quantitative Yield; Diallyl;
D O I：
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中图分类号：
学科分类号：
摘要：
Isomerization of triallylamine in the system KOH-DMSO at 90-100°C leads to formation of tris-(1-propenyl)amine in quantitative yield. Under similar conditions, diallyl(ethyl)amine is converted into ethyl-bis(1-propenyl)amine, 1-ethyl-3-methylcyclohexane. Diallylamine in KOH-DMSO gives rise to a complexmixture of products consisting of bis(1-propenyl)amine, methylbis(1-propenyl)amine, 1-ethyl-3-methylcyclo-hexane, and 2-ethyl-3,5-dimethylpiperidine. Ways of formation of these products are discussed.
引用
收藏
页码：915 / 918
页数：3
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