The photolytic reaction between [ReN(H2O)(CN)4]2− and 1,2-ethanediamine. The crystal structure of tetraphenylphosphonium μ-1,2-ethanediamine-N,N′-bis[tetracyanonitridorhenate(V)] tetrahydrate

被引：0

作者：

Hendrik J. van der Westhuizen

Walter Purcell

Stephen S. Basson

机构：

[1] University of the Free State,Department of Chemistry

来源：

Transition Metal Chemistry | 2002年 / 27卷

关键词：

Crystal Structure; Diffraction Data; Structure Determination; Rhenium; Equatorial Plane;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

An aqueous solution of [ReN(H2O)(CN)4]2− and 1,2-ethanediamine was irradiated in a photolytic reactor. The reaction product, which was isolated as yellow crystals suitable for X-ray structure determination, is a novel complex with the 1,2-ethanediamine acting as a bridge between two rhenium atoms. The crystal structure of (PPh4)4[{ReN(CN)4}2(μ-en)] · 4H2O was determined from three-dimensional X-ray diffraction data. The [{ReN-(CN)4}2(μ-en)]4− anion has a distorted octahedral geometry around both rhenium atoms with Re(1) displaced by 0.35 and Re(2) by 0.31 Å towards the respective nitrido ligands from the equatorial planes formed by the carbon atoms of the four cyano ligands of each rhenium atom.

引用

页码：506 / 511

页数：5

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