Pulsed NMR method for determining the thermodynamic characteristics of adsorption processes in biopolymers

被引：0
|
作者：
Yu. B. Grunin
L. Yu. Grunin
E. A. Nikol’skaya
机构：
[1] Mari State Technical University,
来源：
Russian Journal of Physical Chemistry A | 2007年 / 81卷
关键词：
Cellulose; Adsorption Layer; Lattice Relaxation; Cellulose Sample; Cellulose Surface;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The efficiency of the pulsed NMR method in studying phenomena in the interphase layer of biopolymer-water systems within the framework of the Gibbs thermodynamic theory was examined. Relationships between the nuclear magnetic relaxation times and the chemical potential and surface tension coefficient at the interphase interface of the adsorption system were established. How the thermodynamic and relaxation parameters change during the formation of the adsorption Gibbs layer on various cellulose samples was demonstrated. An analysis of the state of the water in the adsorption layer was performed, and its mean thickness was determined.
引用
收藏
页码：1165 / 1169
页数：4
相关论文
共 50 条
  • [1] Pulsed NMR method for determining the thermodynamic characteristics of adsorption processes in biopolymers
    Grunin, Yu. B.
    Grunin, L. Yu.
    Nikol'skaya, E. A.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 81 (07) : 1165 - 1169
  • [2] METHOD FOR DETERMINING ADSORPTION CHARACTERISTICS
    MINAEV, YA
    INDUSTRIAL LABORATORY, 1971, 37 (06): : 893 - &
  • [3] A thermodynamic method for determining the cavitation characteristics of pumps
    Klimovskii K.K.
    Pinke I.M.
    Thermal Engineering, 2006, 53 (2) : 134 - 137
  • [4] Determining the sizes of micropores in activated charcoals by the pulsed NMR method
    Gogelashvili, G. Sh.
    Khozina, E. V.
    Vartapetyan, R. Sh.
    Ladychuk, D. V.
    Grunin, Yu. B.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (07) : 1237 - 1241
  • [5] Determining the sizes of micropores in activated charcoals by the pulsed NMR method
    G. Sh. Gogelashvili
    E. V. Khozina
    R. Sh. Vartapetyan
    D. V. Ladychuk
    Yu. B. Grunin
    Russian Journal of Physical Chemistry A, 2011, 85 : 1237 - 1241
  • [6] Methods for determining the intrinsic kinetic characteristics of irreversible adsorption processes
    Constales, Denis
    Fang, Zongtang
    Kunz, M. Ross
    Yablonsky, Gregory
    Fushimi, Rebecca
    CHEMICAL ENGINEERING SCIENCE, 2019, 207 : 344 - 351
  • [7] METHOD FOR DETERMINING PITCH ADSORPTION CHARACTERISTICS OF MINERAL POWDERS
    HUGHES, DA
    TAPPI, 1977, 60 (07): : 144 - 146
  • [8] CHROMATOGRAPHIC METHOD FOR DETERMINING THE PHYSICOCHEMICAL AND THERMODYNAMIC CHARACTERISTICS OF COLLOIDAL SYSTEMS
    LEONTYEVA, SA
    TIMOFEEVA, AN
    JOURNAL OF CHROMATOGRAPHY, 1986, 365 : 391 - 397
  • [9] PULSED NMR METHOD FOR DETERMINING SOLID FAT-CONTENT - COLLABORATIVE STUDY
    MELLEMA, JH
    MADISON, BL
    MANNING, RG
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1980, 57 (02) : A150 - A150
  • [10] CHARACTERISTICS OF THERMODYNAMIC PROCESSES
    KARAVAEV, SN
    ZHURNAL FIZICHESKOI KHIMII, 1991, 65 (11): : 3089 - 3091
12345