Kinetic Parameters of Thermal Decomposition of Furazano-1,2,3,4-Tetrazine-1,3-Dioxide and a Binary Solution Based on It

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作者
N. V. Murav’ev
K. A. Monogarov
V. E. Zarko
P. I. Kalmykov
A. N. Pivkina
机构
[1] Russian Academy of Sciences,Semenov Institute of Chemical Physics
[2] Russian Academy of Sciences,Voevodsky Institute of Chemical Kinetics and Combustion
[3] Altai Federal Research and Production Center,undefined
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关键词
FTDO; DNP; differential scanning calorimetry; kinetic parameters; thermal decomposition;
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摘要
The kinetic parameters of thermal decomposition of furazano-1,2,3,4-tetrazine-1,3-dioxide (FTDO) and the (75/25) FTDO/dinitrazapentane (DNP) system were experimentally investigated by differential scanning calorimetry. Kissinger kinetic analysis was performed using differential scanning calorimetry data obtained at heating rates of 0.1–5.0 K/min. The thermal decomposition of FTDO and the FTDO/DNP system is found to be a first-order reaction with an activation energy of 185 (FTDO) and 171 kJ/mol (FTDO/DNP).
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页码:629 / 631
页数:2
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