Columinescence effect in macromolecular complexes of Eu(III) and Tb(III)

被引：0

作者：

N. V. Petrochenkova

A. G. Mirochnik

P. A. Zhikhareva

V. E. Karasev

机构：

[1] Nevelskii Marine State University,Institute of Chemistry, Far East Branch

[2] Russian Academy of Sciences,undefined

来源：

Russian Journal of Physical Chemistry A | 2010年 / 84卷

关键词：

Mixed Metal; Macromolecular Complex; Luminescence Excitation Spectrum; Stark Transition; Mixed Metal Complex;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The effect of Y(III) and Gd(III) coactivator ions on the intensity of Eu(III) and Tb(III) luminescence in monomer and polymer mixed-metal complexes was studied. Isomorphic replacement of Eu(III) and Tb(III) ions by Y(III) and Gd(III) ions in macromolecular complexes led to sensitization of Eu(III) and Tb(III) ion luminescence. A mechanism of columinescence was suggested. It involves a charge transfer and the ligand orbitals and the vacant orbitals of Eu(III) and Tb(III) ions and coactivators.

引用

页码：1628 / 1630

页数：2

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