Synthesis of a new monomer for sulfonated poly(arylene ether sulfones)

被引：0
|
作者：
R. S. Begunov
A. N. Valyaeva
A. N. Fakhrutdinov
S. A. Pirogova
机构：
[1] P. G. Demidov Yaroslavl State University,N. D. Zelinsky Institute of Organic Chemistry
[2] Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2017年 / 66卷
关键词：
poly(arylene ether sulfones); retrosynthetic analysis; aromatic nucleophilic substitution; sulfonation;
D O I：
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中图分类号：
学科分类号：
摘要：
4-({2,4-Bis[(4-chlorophenyl)sulfonyl]phenyl}thio)benzenesulfonic acid was synthesized based on the scheme suggested from the results of retrosynthetic analysis. This compound is a new monomer for the preparation of sulfonated poly(arylene ether sulfones) used as a solid polymer electrolyte in fuel cells. The structure of the aromatic disulfone containing a sulfo group was suggested based on the data on the influence of chemical structure of structural elements of polysulfone proton-conducting membranes on their operational characteristics.
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页码：545 / 551
页数：6
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