Prenylated indole alkaloids from co-culture of marine-derived fungi Aspergillus sulphureus and Isaria felina

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作者：
Shamil Sh. Afiyatullov
Olesya I. Zhuravleva
Alexandr S. Antonov
Dmitrii V. Berdyshev
Mikhail V. Pivkin
Vladimir A. Denisenko
Roman S. Popov
Andrey V. Gerasimenko
Gunhild von Amsberg
Sergey A. Dyshlovoy
Elena V. Leshchenko
Anton N. Yurchenko
机构：
[1] Far Eastern Branch of the Russian Academy of Sciences,G.B. Elyakov Pacific Institute of Bioorganic Chemistry
[2] Far Eastern Federal University,Institute of Chemistry
[3] Far Eastern Branch of the Russian Academy of Sciences,Laboratory of Experimental Oncology, Department of Oncology, Hematology and Bone Marrow Transplantation with Section Pneumology, Hubertus Wald
[4] University Medical Center Hamburg-Eppendorf,Tumorzentrum
来源：
The Journal of Antibiotics | 2018年 / 71卷
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摘要：
Five new prenylated indole alkaloids, 17-hydroxynotoamide D (1), 17-O-ethylnotoamide M (2), 10-O-acetylsclerotiamide (3), 10-O-ethylsclerotiamide (4), and 10-O-ethylnotoamide R (5) were isolated from a co-culture of marine-derived fungi Aspergillus sulphureus KMM 4640 and Isaria felina KMM 4639. The structures of 1−5 were determined by detailed analysis of spectroscopic data and by comparison with related known compounds. The absolute configurations of 1−5 were determined by time-dependent density functional theory (TD-DFT) calculations of ECD spectra. Compound 2 is able to inhibit the colony formation of human prostate cancer cells 22Rv1 at non-cytotoxic concentration of 10 μM.
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页码：846 / 853
页数：7
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