Structures of the complex ions [CuCl4]2− and [CuCl5]3−

被引：0

作者：

Yu. V. Rakitin

V. T. Kalinnikov

S. G. Khodasevich

V. M. Novotortsev

机构：

[1] Russian Academy of Sciences,Tananaev Institute of Rare Element and Mineral Chemistry and Technology, Kola Research Center

[2] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry

来源：

Russian Journal of Coordination Chemistry | 2007年 / 33卷

关键词：

CuCl; Coordination Chemistry; Trigonal Bipyramid; Cambridge Crystallographic Data Center; Packing Effect;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The electronic structures of the complex ions [CuCl4]2− and [CuCl5]3− were analyzed in terms of the extended angular overlap model (AOM) with consideration to sd and pd mixing. The total antibonding orbital energies of these ions show no anomalies in the transition from a tetrahedron to a planar square [CuCl4]2− and from a trigonal bipyramid to a tetragonal pyramid [CuCl5]3−. Presumably, the existence of numerous intermediate forms of these complexes is mainly due to the packing effects rather than the electronic factors.

引用

页码：891 / 895

页数：4

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