Synthesis and structure of nalidixium tetrachloroantimonate monohydrate, (C12H13N2O3)SbCl4 · H2O

被引：0
|
作者：
A. V. Gerasimenko
A. V. Polishchuk
L. M. Volkova
E. T. Karaseva
V. E. Karasev
机构：
[1] Russian Academy of Sciences,Institute of Chemistry, Far East Division
来源：
Russian Journal of Coordination Chemistry | 2008年 / 34卷
关键词：
Coordination Chemistry; Nalidixic Acid; Lone Electron Pair; Carboxy Group; SbCl5;
D O I：
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学科分类号：
摘要：
Nalidixium tetrachloroantimonate monohydrate, (C12H13N2O3)SbCl4 · H2O, has been synthesized and its crystal structure has been determined. The structure is built of the [Sb2Cl8]2− anions, C12H13N2O3+ nalidixium cations, and H2O molecules joint by hydrogen bonds and π-π-and Cl⋯Cl interactions. The [Sb2Cl8]2− anion is a dimer of the SbCl5E distorted octahedra sharing common Cl⋯Cl edge (E is the lone electron pair). The Sb polyhedra contain two short Sb-Cl bonds (2.387 and 2.395 Å), one bond of a medium length (2.508 Å), and two long bridging bonds (2.745 and 3.054 Å).
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页码：8 / 13
页数：5
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