Non-catalytic liquid phase oxidation of alkenes with nitrous oxide. 1. Oxidation of cyclohexene to cyclohexanone

被引：0
|
作者：
Gennady I. Panov
Konstantin A. Dubkov
Evgeny V. Starokon
Valentin N. Parmon
机构：
[1] Boreskov Institute of Catalysis,
来源：
Reaction Kinetics and Catalysis Letters | 2002年 / 76卷
关键词：
oxidation; cyclohexene; Cyclohexanone; nitrous oxide;
D O I：
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中图分类号：
学科分类号：
摘要：
A very efficient way of alkenes oxidation to carbonyl compounds is discovered. It is based on remarkable ability of nitrous oxide to interact directly with the double C=C bonds of liquid alkene and to transfer its oxygen, without catalyst aid, to unsaturated carbon atom with nearly 100% selectivity. This oxidation method can be applied to a wide range of organic compounds including aliphatic, cyclic, heterocyclic alkenes and their numerous derivatives.
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页码：401 / 406
页数：5
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