Synthesis of oligo-6-bromo-6-deoxy-β-cyclodextrins

被引:0
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作者
G. I. Kurochkina
I. Yu. Trushkin
M. K. Grachev
E. E. Nifant’ev
机构
[1] Moscow State Pedagogical University,
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关键词
Bromine; Hydroxy Group; Tosyl; Bromine Atom; Onset Point;
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摘要
Two methods of synthesis of oligo-6-bromo-6-deoxy-β-cyclodextrins, with use of the Vilsmeier-Haack reagent and via tosyl derivatives of β-cyclodextrin, were compared. The second method holds more promise, since it allows a desired number of bromine atoms to be introduced into the β-cyclodextrin molecule instead of hydroxy groups. A correlation between the decomposition onset points of oligo-6-bromo-6-deoxy-β-cyclodextrins and the number of bromine substituents in them was revealed.
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页码:1620 / 1622
页数:2
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