Ethylene carbonate production by cyclocondensation of ethylene glycol and urea in the presence of metal oxides and metal acetylacetonates

被引:0
|
作者
A. S. Lyadov
A. A. Kochubeev
E. B. Markova
S. N. Khadzhiev
机构
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
来源
Petroleum Chemistry | 2016年 / 56卷
关键词
ethylene carbonate; ethylene glycol; urea; metal oxides; metal acetylacetonates;
D O I
暂无
中图分类号
学科分类号
摘要
A promising method for the production of ethylene carbonate is the cyclocondensation of ethylene glycol and urea in the presence of a catalyst. In this study, the catalytic effect of oxides and acetylacetonates of various metals on the occurrence of this reaction has been examined. It has been shown that cobalt acetylacetonate is the most effective catalyst. The effect of reaction conditions (temperature, pressure, contact time, and catalyst concentration) on the main parameters of catalytic conversion has been studied.
引用
收藏
页码:852 / 856
页数:4
相关论文
共 50 条
  • [31] METAL ION COMPLEXES OF 2-IMIDAZOLIDINONE (ETHYLENE UREA)
    BERNI, RJ
    BENERITO, RR
    AYRES, WM
    JONASSEN, HB
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1963, 25 (07): : 807 - 818
  • [32] Acetate stabilization of metal nanoparticles and its role in the preparation of metal nanoparticles in ethylene glycol
    Yang, J
    Deivaraj, TC
    Too, HP
    Lee, JY
    LANGMUIR, 2004, 20 (10) : 4241 - 4245
  • [33] HYDROCARBALKOXYLATION OF ETHYLENE IN PRESENCE OF METAL-ZEOLITE CATALYSTS
    NEFEDOV, BK
    KOZHUKHAREVA, VN
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1977, 26 (10): : 2114 - 2116
  • [34] Decomposition of ethylene carbonate on electrodeposited metal thin film anode
    Bridel, Jean-Sebastien
    Grugeon, Sylvie
    Laruelle, Stephane
    Hassoun, Jusef
    Reale, Priscilla
    Scrosati, Bruno
    Tarascon, Jean-Marie
    JOURNAL OF POWER SOURCES, 2010, 195 (07) : 2036 - 2043
  • [35] ETHYLENE GLYCOL-DIMETHYL CARBONATE COGENERATION
    DURANLEAU, RG
    KNIFTON, JF
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 94 - PETR
  • [36] ETHYLENE CARBONATE - COMMERCIAL PRODUCTION
    SPRINGMA.H
    FETTE SEIFEN ANSTRICHMITTEL VERBUNDEN MIT DER ZEITSCHRIFT DIE ERNAHRUNGSINDUSTRIE, 1970, 72 (11): : 949 - &
  • [37] ETHYLENE-GLYCOL DIMETHYL CARBONATE COGENERATION
    KNIFTON, JF
    DURANLEAU, RG
    JOURNAL OF MOLECULAR CATALYSIS, 1991, 67 (03): : 389 - 399
  • [38] TECHNICAL PRODUCTION OF ETHYLENE CARBONATE
    SPRINGMAN, H
    FETTE SEIFEN ANSTRICHMITTEL VERBUNDEN MIT DER ZEITSCHRIFT DIE ERNAHRUNGSINDUSTRIE, 1971, 73 (06): : 396 - +
  • [39] HYDROGENATION AND ACETALIZATION OF CYCLOHEXANONE OVER PLATINUM GROUP METAL-CATALYSTS IN THE PRESENCE OF ETHYLENE-GLYCOL
    ISHIYAMA, J
    ESASHIKA, K
    SENDA, Y
    IMAIZUMI, S
    NIPPON KAGAKU KAISHI, 1988, (01) : 126 - 128
  • [40] Thermal transformations of urea in ethylene glycol: II. Reaction of isocyanic acid with ethylene glycol associates
    Samuilov, A. Ya.
    Valeev, A. R.
    Balabanova, F. B.
    Samuilov, Ya. D.
    Konovalov, A. I.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 49 (12) : 1723 - 1727