Kinetics of thermal decomposition of dimethyldioxirane in oxygen atmosphere

被引：0
|
作者：
S. A. Grabovski
D. V. Kazakov
N. N. Kabalnova
S. L. Khursan
V. V. Shereshovets
机构：
[1] Academy of Sciences,Institute of Organic Chemistry, Ufa Research Center of the Russian
来源：
Reaction Kinetics and Catalysis Letters | 1997年 / 62卷
关键词：
Dioxiranes; kinetics; thermolysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Dimethyldioxirane decomposition in oxygen atmosphere follows a first-order kinetic law. Decomposition rate constant (k, s−1) in acetone in the temperature range from 30 to 50°C has been determined as lgk=(7.1±0.9)−(16.0±1.4)/θ, θ=2.303RT kcal/mol.
引用
收藏
页码：179 / 183
页数：4
相关论文
共 50 条
  • [31] Thermal decomposition characteristics and kinetics of methyl linoleate under nitrogen and oxygen atmospheres
    Xue-Chun Wang
    Jian-Hua Fang
    Bo-Shui Chen
    Jiu Wang
    Jiang Wu
    Di Xia
    Petroleum Science, 2015, (03) : 518 - 524
  • [32] Thermal decomposition characteristics and kinetics of methyl linoleate under nitrogen and oxygen atmospheres
    Wang, Xue-Chun
    Fang, Jian-Hua
    Chen, Bo-Shui
    Wang, Jiu
    Wu, Jiang
    Xia, Di
    PETROLEUM SCIENCE, 2015, 12 (03) : 518 - 524
  • [33] Thermal decomposition characteristics and kinetics of methyl linoleate under nitrogen and oxygen atmospheres
    Xue-Chun Wang
    Jian-Hua Fang
    Bo-Shui Chen
    Jiu Wang
    Jiang Wu
    Di Xia
    Petroleum Science, 2015, 12 (03) : 518 - 524
  • [34] THE KINETICS OF THE THERMAL DECOMPOSITION OF POTASSIUM NITRATE AND OF THE REACTION BETWEEN POTASSIUM NITRITE AND OXYGEN
    FREEMAN, ES
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (04) : 838 - 842
  • [35] INDOLE DIOXETANES AND EPOXIDES BY OXIDATION OF N-ACYLATED INDOLES WITH SINGLET OXYGEN AND DIMETHYLDIOXIRANE - KINETICS AND CHEMILUMINESCENCE YIELDS OF THE THERMAL DIOXETANE DECOMPOSITION AND FLUORIDE ION-INDUCED CIEEL EMISSION
    ADAM, W
    REINHARDT, D
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (07): : 1503 - 1507
  • [36] THE KINETICS OF THE THERMAL DECOMPOSITION OF SODIUM NITRATE AND OF THE REACTION BETWEEN SODIUM NITRITE AND OXYGEN
    FREEMAN, ES
    JOURNAL OF PHYSICAL CHEMISTRY, 1956, 60 (11): : 1487 - 1493
  • [37] Kinetics of thermal decomposition of aluminium hydride: I-non-isothermal decomposition under vacuum and in inert atmosphere (argon)
    Ismail, IMK
    Hawkins, T
    THERMOCHIMICA ACTA, 2005, 439 (1-2) : 32 - 43
  • [38] Kinetics Study of the Thermal Decomposition of Post-consumer Poly(Ethylene Terephthalate) in an Argon Atmosphere
    Hamidi, Nasrollah
    JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2019, 58 (02): : 219 - 247
  • [39] The theoretical trajectory for the chloride-ion-induced generation of singlet oxygen in the decomposition of dimethyldioxirane
    Ovchinnikov, Mikhail Yu.
    Khursan, Sergey L.
    Kazakov, Dmitri V.
    Adam, Waldemar
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2010, 210 (2-3) : 100 - 107
  • [40] DECOMPOSITION/VOLATILIZATION OF ENARGITE IN NITROGEN - OXYGEN ATMOSPHERE
    Padilla, Rafael
    Aracena, Alvaro
    Cristina Ruiz, Maria
    TMS 2010 139TH ANNUAL MEETING & EXHIBITION - SUPPLEMENTAL PROCEEDINGS, VOL 1: MATERIALS PROCESSING AND PROPERTIES, 2010, : 497 - 504
12345