Kinetics of thermal decomposition of dimethyldioxirane in oxygen atmosphere

被引：0
|
作者：
S. A. Grabovski
D. V. Kazakov
N. N. Kabalnova
S. L. Khursan
V. V. Shereshovets
机构：
[1] Academy of Sciences,Institute of Organic Chemistry, Ufa Research Center of the Russian
来源：
Reaction Kinetics and Catalysis Letters | 1997年 / 62卷
关键词：
Dioxiranes; kinetics; thermolysis;
D O I：
暂无
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学科分类号：
摘要：
Dimethyldioxirane decomposition in oxygen atmosphere follows a first-order kinetic law. Decomposition rate constant (k, s−1) in acetone in the temperature range from 30 to 50°C has been determined as lgk=(7.1±0.9)−(16.0±1.4)/θ, θ=2.303RT kcal/mol.
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页码：179 / 183
页数：4
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