A Novel 3D Platinum–Thallium Coordination Polymer having Strong Metal–Metal Interactions

被引：0
|
作者：
Guoqiang Wu
Daqi Wang
机构：
[1] West Branch of Zhejiang University of Technology,Department of Chemical Engineering
[2] Liaocheng University,Department of Chemistry
来源：
Journal of Cluster Science | 2007年 / 18卷
关键词：
Platinum; thallium; coordination polymer; metal–metal interaction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new three-dimensional platinum(II)–thallium(I) coordination polymer [{Pt(pda)(NHCOtBu)2}4Tl4][Pt(CN)4]2·2H2O (pda = 1,2-propyldiamine) has been prepared from the direct reaction of [Tl2Pt(CN)4] and [Pt(pda)(NHCOtBu)2] in water, and its structure was characterized by X-ray diffraction analysis. The compound crystallizes in monoclinic, space group Pn, a = 11.567(2) Å, b = 11.570(2) Å, c = 37.677(8)Å, β = 94.64(3)°, V = 5025.8(17) Å3, Z = 2, R1 = 0.0679 and wR2 = 0.1574 [I >  2σ (I)], Goodness-of-fit on F2 = 1.055. The compound exhibits a novel 3D network structure consisting of [Pt(CN)4]2− connected 1D infinite Pt–Tl–Pt–Tl chains via strong Pt–Tl bonds.
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页码：406 / 413
页数：7
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