Solution-combustion synthesis of oxide nanoparticles from nitrate solutions containing glycine and urea: Thermodynamic aspects

被引：21

作者：

Khaliullin S.M. ^{[1
]}

Zhuravlev V.D. ^{[1
]}

Bamburov V.G. ^{[1
]}

机构：

[1] Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg

来源：

International Journal of Self-Propagating High-Temperature Synthesis | 2016年 / 25卷 / 3期

关键词：

adiabatic reaction; glycine; ionic radius; metal oxides; solution-combustion synthesis (SCS); temperature effect; urea;

D O I：

10.3103/S1061386216030031

中图分类号：

学科分类号：

摘要：

Solution-combustion synthesis (SCS) of nanoparticles was characterized by the temperature effect (ΔTad) calculated upon neglect by the temperature dependence of heat capacity. Thus calculated ΔTad values were found to be a linear function of the inverse radius of metal ions. Our calculations have shown that SCS reactions may yield not only oxides but also hydroxides and carbonates. Suggested was a simple formula for evaluating the ΔTad values attained in SCS of complex oxides. © 2016, Allerton Press, Inc.

引用

页码：139 / 148

页数：9

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