Identification of an iridium-containing compound with a formal oxidation state of IX

被引：0
|
作者：
Guanjun Wang
Mingfei Zhou
James T. Goettel
Gary J. Schrobilgen
Jing Su
Jun Li
Tobias Schlöder
Sebastian Riedel
机构：
[1] Collaborative Innovation Center of Chemistry for Energy Materials,Department of Chemistry
[2] Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials,Department of Chemistry
[3] Fudan University,Department of Chemistry and Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education
[4] McMaster University,undefined
[5] 1280 Main Street West,undefined
[6] Hamilton,undefined
[7] Ontario L8S 4M1,undefined
[8] Canada,undefined
[9] Tsinghua University,undefined
[10] Beijing 100084,undefined
[11] China,undefined
[12] Institut für Anorganische und Analytische Chemie,undefined
[13] Albert-Ludwigs Universität Freiburg,undefined
[14] Albertstrasse 21,undefined
[15] D-79104 Freiburg im Breisgau,undefined
[16] Germany,undefined
[17] Institut für Chemie und Biochemie – Anorganische Chemie,undefined
[18] Freie Universität Berlin,undefined
[19] Fabeckstrasse 34-36,undefined
[20] D-14195 Berlin,undefined
[21] Germany,undefined
来源：
Nature | 2014年 / 514卷
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学科分类号：
摘要：
The tetrahedral iridium tetroxide cation [IrO4]+, which has an iridium 5d0 valence electron configuration and a formal oxidation state of IX, is generated in the gas phase, identified by infrared photodissociation spectroscopy, and predicted, by quantum chemical calculations, to be the most stable of all possible [IrO4]+ isomers.
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页码：475 / 477
页数：2
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