New bis-macrocyclic complexes with transition metal ions

被引：0
|
作者：
Ashok Kumar Singh
Amit Panwar
Rupam Singh
Seema Baniwal
机构：
[1] Indian Institute of Technology,Department of Chemistry
来源：
Transition Metal Chemistry | 2003年 / 28卷
关键词：
Physical Chemistry; Formaldehyde; Inorganic Chemistry; Magnetic Susceptibility; Diene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Template condensation of benzidine, formaldehyde, ethylenediamine or 1,3-diaminopropane, metal salt and 1-phenyl-1,3-butanedione or 2,3-butanedione in a 1:4:2:2 molar ratio results in the formation of two new series of binuclear pentaaza macrocyclic complexes: dichloro[1,1′-phenylbis(7-methyl-9-phenyl-1,3,6,10,13-pentaazacyclotetradeca-6,9-diene) metal(II)], [M2LCl4] (M = CoII, CuII, FeIII and ZnII) and dichloro[1,1′-phenylbis(8,9-dimethyl-1,3,7,10,14-pentaazacyclopentadeca-7,9-diene) metal(II)], [M2L′Cl4] (M = NiII, CoII, CuII and CdII). Both series were characterized by i.r., 1H-n.m.r., u.v.–vis. spectral studies, conductivity and magnetic susceptibility measurements.
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页码：160 / 162
页数：2
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