Sorption of Water, Methanol, and Hexane Vapors by Crystalline Carboxylates of bis-Macrocyclic Copper(II) Complexes

被引：0
|
作者：
L. V. Tsymbal
I. L. Andriichuk
P. S. Yaremov
V. G. Ilyin
Ya. D. Lampeka
机构：
[1] National Academy of Sciences of Ukraine,L. V. Pisarzhevskii Institute of Physical Chemistry
来源：
Theoretical and Experimental Chemistry | 2014年 / 50卷
关键词：
copper(II); macrocyclic complexes; aromatic carboxylates; adsorption; water; methanol; hexane;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
We have established that a typical feature of adsorption processes involving participation of porous ionic crystalline compounds formed by cations of bis-macrocyclic copper(II) complexes is absorption/desorption hysteresis, associated with significant rearrangement of the lattices of the complexes during adsorption/desorption. The compounds studied have high sorption capacity for water and methanol, comparable with that of porous coordination polymers.
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页码：250 / 256
页数：6
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