Features of the oxidation of certain hydroxy derivatives of ferrocene with molecular oxygen in organic solvents

被引：0
|
作者：
V. M. Fomin
A. E. Shirokov
N. G. Polyakova
机构：
[1] Lobachevskii Nizhny Novgorod State University,
来源：
Russian Journal of General Chemistry | 2008年 / 78卷
关键词：
General Chemistry; Ferrocene; Peroxide Radical; Mutual Approach; Radical Chain Oxidation;
D O I：
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中图分类号：
学科分类号：
摘要：
Features of the oxidation of hydroxymethylferrocene with molecular oxygen in organic solvent in the presence of weak and strong Broensted acids were studied. The resulting data were compared with published data on ferrocene and hydroxyferrocene oxidation, which made it possible to assess the trend in the oxidation mechanism in going from ferrocene π complexes to their hydroxyferrocene and hydroxymethylferrocene analogs. A conclusion was drawn that each of the ferrocenes reacts with oxygen in quite a specific way.
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页码：1361 / 1370
页数：9
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