Generalization of Data on Solvent Effect on Formation of Charge-Transfer Complexes Using Linear Multiparameter Equations

被引:0
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作者
R. G. Makitra
I. P. Polyuzhin
I. P. Shevchuk
机构
[1] National Academy of Sciences of Ukraine,Division of Physical Chemistry and Technology of Fossil Fuels, Pisarzhevskii Institute of Physical Chemistry
[2] Lvovskaya Polytechnika National University,undefined
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关键词
Correlation Analysis; Equilibrium Constant; Solvent Polarity; Solvent Effect; Solvent Property;
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摘要
The correlation analysis of data on the equilibrium constants of formation of various charge-transfer complexes (Ke) in various solvents shows that the solvent polarity alone does not provide sufficiently reliable description of the process. An adequate correlation between Ke and solvent properties can be obtained only with combined consideration of the capability of solvents for specific and nonspecific solvation.
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页码:177 / 180
页数:3
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