Navy-to-transmissive electrochromic polymer based on 3,4-propylenedioxythiophene

被引:0
|
作者
Xiaoming Chen
Jingyan Zhang
Mingdi Yang
机构
[1] Anhui Jianzhu University,Anhui Key Laboratory of Advanced Building Materials, School of Materials & Chemical Engineering
来源
Journal of Materials Science: Materials in Electronics | 2018年 / 29卷
关键词
D O I
暂无
中图分类号
学科分类号
摘要
A novel conjugated polymer PProDOTCBDEM based on propylenedioxythiophene (ProDOT) with diethyl malonate (DEM) pendant group and a cyclobutane spacer between ProDOT and DEM was successfully synthesized through electrochemical polymerization. The polymer film exhibits reversible electrochromism switching between navy neutral state (− 0.1 V) and transmissive oxidized state (0.7 V). The symmetric double short chain ester substitution pattern was utilized to realize the navy color of the polymer film. The electrochemistry, spectroelectrochemistry and electrochromic switching properties of the polymer film were studied in detail.
引用
收藏
页码:16469 / 16477
页数:8
相关论文
共 50 条
  • [21] Synthesis and characterization of monosubstituted and disubstituted poly (3,4-propylenedioxythiophene) derivatives with high electrochromic contrast in the visible region
    Mishra, SP
    Krishnamoorthy, K
    Sahoo, R
    Kumar, A
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (02) : 419 - 428
  • [22] Superhydrophobic surfaces from 3,4-propylenedioxythiophene (ProDOT) derivatives
    Guittard, F. (guittard@unice.fr), 1600, Elsevier Ltd (49):
  • [23] Superhydrophobic surfaces from 3,4-propylenedioxythiophene (ProDOT) derivatives
    Wolfs, Melanie
    Darmanin, Thierry
    Guittard, Frederic
    EUROPEAN POLYMER JOURNAL, 2013, 49 (08) : 2267 - 2274
  • [24] A colorimetric Fe3+ sensor based on an anionic poly(3,4-propylenedioxythiophene) derivative
    Chen, Xiaoming
    Zhao, Qingchun
    Zou, Wensheng
    Qu, Qishu
    Wang, Feng
    SENSORS AND ACTUATORS B-CHEMICAL, 2017, 244 : 891 - 896
  • [25] Acrylated Poly(3,4-propylenedioxythiophene) for Enhancement of Lifetime and Optical Properties for Single-Layer Electrochromic Devices
    Otley, Michael T.
    Alamer, Fahad Alhashmi
    Zhu, Yumin
    Singhayiranon, Ashwin
    Zhang, Xiaozheng
    Li, Mengfang
    Kumar, Amrita
    Sotzing, Gregory A.
    ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (03) : 1734 - 1739
  • [26] Continuous Flow Synthesis of Substituted 3,4-Propylenedioxythiophene Derivatives
    Tarange, Dattatray L.
    Nayak, Nagaraj
    Kumar, Anil
    ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2023, 27 (02) : 358 - 366
  • [27] Achieving the gray to transparent switching electrochromic properties based on the diketopyrrolopyrrole, 3,4-propylenedioxythiophene and thieno[3,2-b]thiophene units
    Yue, Haoguo
    Ming, Shouli
    Du, Hongmei
    Zhao, Jinsheng
    Zhang, Yan
    EUROPEAN POLYMER JOURNAL, 2022, 175
  • [28] Synthesis and characterization of regiosymmetric poly(3,4-propylenedioxythiophene) derivative
    Shin, W
    Kim, MK
    Jin, SH
    Shim, YB
    Lee, JK
    Lee, JW
    Gal, YS
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2006, 444 : 129 - 135
  • [30] Specroelectrochemical, Switching Kinetics, and Chronoamperometric Studies of Dibenzyl Derivative of Poly(3,4-propylenedioxythiophene) Thin-Film-Based Electrochromic Device
    Lakshmanan, Raja
    Raja, Palani Prabhu
    Shivaprakash, Narayanapura Channegowda
    Nair, Sindhu Sukumaran
    JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (17) : 8813 - 8819