Extraction distribution of microamounts of strontium in the two-phase water-KCl-15-crown-5-nitrobenzene-potassium dicarbollylcobaltate system

被引:0
|
作者
Vaňura P. [1 ]
Makrlík E. [2 ]
Selucký P. [3 ]
机构
[1] Prague Institute of Chemical Technology, 166 28 Prague 6
[2] Faculty of Applied Sciences, University of West Bohemia, 306 14 Pilsen
[3] Nuclear Research Institute
关键词
Potassium; Physical Chemistry; Inorganic Chemistry; Strontium; Organic Phase;
D O I
10.1007/s10967-006-0143-4
中图分类号
学科分类号
摘要
Extraction of microamounts of strontium by a nitrobenzene solution of potassium dicarbollylcobaltate (K+B-) in the presence of 15-crown-5 (15C5, L) has been investigated. The equilibrium data have been explained assuming that the complexes KL+, KL2+ and SrL22+ are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. © 2006 Akadémiai Kiadó.
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页码:159 / 162
页数:3
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