Synthesis, structure, luminescence and magnetic properties of the coordination polymer {[Eu(H2O)5][Mo(CN)8]}∞ containing bridging cyanide ligands

被引:0
|
作者
E. N. Chelebaeva
A. A. Trifonov
J. E. Larionova
Y. Guari
R. A. Sa Fereira
L. D. Carlos
F. A. Almeida Paz
Ch. Guérin
机构
[1] Russian Academy of Sciences,G. A. Razuvaev Institute of Organometallic Chemistry
[2] University of Montpellier-II,Laboratory of Molecular Chemistry and Solid State Organization, Charles Gerhardt Institute
[3] University of Aveiro,Department of Physics
[4] University of Aveiro,Department of Chemistry and CICECO
来源
Russian Chemical Bulletin | 2010年 / 59卷
关键词
lanthanides; coordination polymers; polycyanometallates; luminescence; magnetism;
D O I
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中图分类号
学科分类号
摘要
The reaction of [Eu(H2O)6](NO3)3 and [N(C4H9)4]3[Mo(CN)8]·2H2O afforded a new two-dimensional coordination polymer {[Eu(H2O)5[Mo(CN)8]}∞ (1) in which the europium and molybdenum atoms are bound through the bridging CN groups. The luminescence and magnetic properties of complex 1 were studied in a wide temperature range.
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页码:476 / 479
页数:3
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