Thermodynamic, Dielectric and Conformational Studies on Hydrogen Bonded Binary Mixtures of Propan-1-ol with Methyl Benzoate and Ethyl Benzoate

被引：0
|
作者：
T. Madhu Mohan
S. Sreehari Sastry
V. R. K. Murthy
机构：
[1] Acharya Nagarjuna University,Department of Physics
[2] Indian Institute of Technology,Department of Physics
来源：
Journal of Solution Chemistry | 2011年 / 40卷
关键词：
Bruggeman parameter; Relaxation time; Hydrogen bond; FT-IR;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Dielectric relaxation studies of propan-1-ol with alkyl benzoates (methyl benzoate and ethyl benzoate) have been carried out, for various mole fractions, at different temperatures using a LF impedance analyzer, Plunger method, and an Abbe’s refractometer in the radio, microwave and optical frequency regions, respectively. Kirkwood’s effective correlation factor, the corrective Kirkwood correlation factor, Bruggeman parameter, relaxation time, excess inverse relaxation time and thermodynamic parameters were calculated using the experimental data. Conformational analysis of the formation of hydrogen bonds in the equi-molar binary mixtures of propan-1-ol with alkyl benzoates is supported by experimental and theoretical FT-IR values.
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页码：131 / 146
页数：15
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