NMR Study of the Inclusion Complexes of Carboxy-Phenoxathiin Derivatives with β-Cyclodextrin

被引：0
|
作者：
Aura Tintaru
Mihaela Hillebrand
André Thevand
机构：
[1] University of Bucharest,Department of Physical Chemistry, Faculty of Chemistry
[2] University of Provence,Laboratory of Physics of Ionic and Molecular Interactions – Spectroscopy and Molecular Dynamics, CNRS 6633
[3] Campus of Saint-Jérôme,undefined
[4] Case 252,undefined
来源：
Journal of inclusion phenomena and macrocyclic chemistry | 2003年 / 45卷
关键词：
inclusion complexes; NMR; ROESY; β-cyclodextrin; phenoxathiin derivatives;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The inclusion complexes of the carboxylate forms of 3-carboxy-(I) and 2-carboxy-phenoxathiin (II) with β-cyclodextrin were studied by bothone- and two-dimensional NMR spectroscopy. The analysis of the induced chemical shifts of theguests in the presence of different amounts of the host indicates the formation of complexes with 1:1stoichiometry and association averaged pK values of 3.75 (I) and 4.4 (II). Thequalitative analysis of cross peaks in the ROESY spectra support the inclusion of the guests in the cavitywith the substituted phenyl ring, the COO- group being in the proximity of the primary rim.
引用
收藏
页码：35 / 40
页数：5
相关论文
共 50 条
  • [41] A REGRESSION STUDY ON THE INCLUSION OF CYCLODEXTRIN WITH BENZENE DERIVATIVES
    Qing Xiang GUO
    Shuang Hui LUO
    Xiao Qi ZHENG
    and You Cheng LIU(Department of Modern Chemistry. University of Science andTechnology of China
    Chinese Chemical Letters, 1996, (08) : 767 - 770
  • [42] Theoretical study on ferrocenyl hydrazones inclusion complexes with β-cyclodextrin and its three methylated derivatives
    Srihakulung, Ornin
    Triamchaisri, Nat
    Toochinda, Pisanu
    Lawtrakul, Luckhana
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2020, 98 (1-2) : 79 - 91
  • [43] Theoretical study on ferrocenyl hydrazones inclusion complexes with β-cyclodextrin and its three methylated derivatives
    Ornin Srihakulung
    Nat Triamchaisri
    Pisanu Toochinda
    Luckhana Lawtrakul
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2020, 98 : 79 - 91
  • [44] Study on the inclusion behavior of coumarin derivatives in β-cyclodextrin
    Dai, Zhaohua
    Wu, Shikang
    Ganguang Kexue yu Guanghuaxue/Photographic Science and Photochemistry, 2000, 18 (01): : 67 - 72
  • [45] Analysis of the thermal fluctuations in inclusion complexes of genistein with β-cyclodextrin derivatives
    Venuti, Valentina
    Corsaro, Carmelo
    Stancanelli, Rosanna
    Paciaroni, Alessandro
    Crupi, Vincenza
    Tommasini, Silvana
    Ventura, Cinzia A.
    Majolino, Domenico
    CHEMICAL PHYSICS, 2019, 516 : 125 - 131
  • [46] STUDY OF THE INCLUSION COMPLEXES OF CYCLODEXTRIN BY CYCLIC VOLTAMMETRY
    DONG, SJ
    ZHANG, DB
    ACTA CHIMICA SINICA, 1988, 46 (04) : 335 - 339
  • [47] Study of inclusion complexes of cyclodextrin by cyclic voltammetry
    DONG Shao-Jun ZHANG Dong-Bo Changchun Institute of Applied Chemistry
    ActaChimicaSinica(EnglishEdition), 1988, (02) : 116 - 122
  • [48] Spectroscopic study of inclusion complexes of β-cyclodextrin with sulfonamides
    Szafran, B
    Pawlaczyk, J
    POLISH JOURNAL OF CHEMISTRY, 1998, 72 (02) : 480 - 484
  • [49] A comprehensive study on flavor/cyclodextrin inclusion complexes
    He, Nan
    Zhang, Chunxiao
    Hou, Kaiyang
    Yu, Hongxiao
    Zhang, Donghai
    Chen, Mengying
    Zhang, Kaiqiang
    Wang, Xu
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2023, 679
  • [50] CYCLODEXTRIN INCLUSION COMPLEXES
    SAENGER, W
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 179 (MAR): : 86 - PHYS
12345