Catalytic oxidation of methanol to methyl formate over silver – a new purpose of a traditional catalysis system

被引：3
|
作者：
Zhi Yang
Jing Li
Xiangguang Yang
Yue Wu
机构：
[1] Chinese Academy of Sciences,Laboratory of Materials and Devices, Changchun Institute of Applied Chemistry
来源：
Catalysis Letters | 2005年 / 100卷
关键词：
formaldehyde; methanol; methyl formate; oxygen species; silver; synergic effect;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Catalytic reaction was performed in the unregarded temperature region over silver catalysts with long catalytic lifetime for the conversion of methanol to methyl formate. Oα-saturated or Oγ-saturated silver catalysts were studied individually to identify the roles of Oα, Oγ in the oxidative esterification of methanol over an unsupported polycrystalline silver catalyst. A synergic process is proposed based on the coexistence of α-oxygen species and γ-oxygen species on the surface of polycrystalline silver at about 573 K.
引用
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页码：205 / 211
页数：6
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