Synthesis and Crystal Structure of the π-Complex 5CuCl⋅Si(O–CH2–CH=CH2)4

被引：0

作者：

V. V. Olijnik

T. P. Korsak

V. N. Davydov

机构：

[1] Ukrainian State Wood Technology University,

[2] I. Franko Lvov State University,undefined

来源：

Journal of Structural Chemistry | 2001年 / 42卷

关键词：

Radiation; Copper; Chloride; Physical Chemistry; Crystal Structure;

D O I：

暂无

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学科分类号：

摘要：

This paper discusses the results of synthesis and X-ray diffraction analysis (DARCH single crystal diffractometer, MoKα radiation) of a π-complex of copper(I) chloride with tetraallyloxysilane 5CuCl⋅Si(O–CH2–CH=CH2)4 (space group P4/n, a = 13.813(2), c = 5.9424(7) Å, Z = 2). Structural data for other olefin complexes of copper(I) are used to analyze the structural effect of the restricted disordering of the guest molecule with conservation of the high general symmetry of the structure introduced by the olefin molecule.

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页码：454 / 458

页数：4

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