Basicity of {(2-amino)- and (2-aminomethyl)bicyclo[2.2.1]hept-3-yl}anilines in nitromethane

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作者
I. A. Novakov
B. S. Orlinson
R. V. Brunilin
E. A. Potaenkova
E. V. Sorokina
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[1] Volgograd State Technical University,
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关键词
Aniline; Diamine; Polyimide; Nitromethane; Adamantane;
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摘要
Ionization constants of {(2-amino)-bicyclo[2.2.1]-hept-3-yl}anilines and {(2-aminomethyl)bicyclo [2.2.1]-hept-3-yl}anilines in nitromethane have been determined by potentiometric titration. Due to high values of pKa 1BH+ and pKa 2BH+ (close to known adamantane-containing diamines) the studied compounds are promising candidates for preparation of (co)polyimides with a complex of excellent utilitarian properties.
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页码:2037 / 2039
页数:2
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