Crystal structure of [CuL](NO3)(ReO4) and [CuL](ReO4)2 (L = 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-en)

被引：0
|
作者：
E. A. Bykova
S. P. Khranenko
E. Yu. Semitut
S. A. Gromilov
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,Research and Education Complex “Nanosystems and Modern Materials,”
来源：
Journal of Structural Chemistry | 2012年 / 53卷
关键词：
copper; rhenium; crystal chemistry; single crystal X-ray diffraction; thermal studies;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The crystal structures of [CuL](NO3)(ReO4) and [CuL](ReO4)2 (L is 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO3)(ReO4) is completed to a distorted octahedron by two oxygen atoms: Cu…O (ReO4−) 2.393 Å and Cu…O (NO3−) 2.685 Å, and that in [CuL](ReO4)2, by Cu…O(ReO4−) 2.468 Å and 2.697 Å. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.
引用
收藏
页码：138 / 144
页数：6
相关论文
共 50 条
  • [1] Crystal structure of [CuL](NO3)(ReO4) and [CuL](ReO4)2 (L=4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-en)
    Bykova, E. A.
    Khranenko, S. P.
    Semitut, E. Yu.
    Gromilov, S. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (01) : 138 - 144
  • [2] Preparation and structure of (Cu(pc))3(ReO4)2 and theoretical investigation of Cu(pc)(ReO4), Cu(pc)(ReO4)2, and (Cu(pc))3(ReO4)2
    Ibers, J.A. (ibers@chem.northwestern.edu), 1600, American Chemical Society (124):
  • [3] Preparation and structure of (Cu(pc))3(ReO4)2 and theoretical investigation of Cu(pc)(ReO4), Cu(pc)(ReO4)2, and (Cu(pc))3(ReO4)2
    Gardberg, AS
    Deng, KM
    Ellis, DE
    Ibers, JA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (19) : 5476 - 5480
  • [4] CRYSTAL STRUCTURE OF [Cu(en)2](ReO4)2
    Shusharina, E. A.
    Khranenko, S. P.
    Gromilov, S. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (01) : 203 - 205
  • [5] Crystal structure of [Cu(en)2](ReO4)2
    Shusharina E.A.
    Khranenko S.P.
    Gromilov S.A.
    Journal of Structural Chemistry, 2011, 52 (1) : 203 - 205
  • [6] STRUCTURAL INVESTIGATION OF [Au(en)2] Cl(ReO4)2 AND [Au(en)2](ReO4)3 COMPLEXES
    Makotchenko, E. V.
    Baidina, I. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (03) : 556 - 559
  • [7] Structural investigation of [Au(en)2]Cl(ReO4) 2 and [Au(en)2](ReO4)3 complexes
    Makotchenko E.V.
    Baidina I.A.
    Journal of Structural Chemistry, 2011, 52 (3) : 556 - 559
  • [8] Crystal structure of [Cu(NH3)4](ReO4)2
    S. P. Khranenko
    E. A. Shusharina
    S. A. Gromilov
    A. I. Smolentsev
    Journal of Structural Chemistry, 2009, 50 : 1201 - 1203
  • [9] Crystal structure of [Cu(NH3)4](ReO4)2
    Khranenko, S. P.
    Shusharina, E. A.
    Gromilov, S. A.
    Smolentsev, A. I.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 50 (06) : 1201 - 1203
  • [10] [Ni(en)3](ReO4)2: Synthesis, crystal structure and thermal properties
    E. A. Bykova
    S. P. Khranenko
    S. A. Gromilov
    Journal of Structural Chemistry, 2012, 53 : 184 - 188
12345