Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine

被引：0

作者：

Sandeep Kumar

Savit Andotra

Mandeep Kaur

Vivek K. Gupta

Rajni Kant

Sushil K. Pandey

机构：

[1] University of Jammu,Department of Chemistry

[2] Department of Physics and Electronics,X

[3] University of Jammu,ray Crystallographic Laboratory

来源：

Crystallography Reports | 2016年 / 61卷

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学科分类号：

摘要：

Complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine [{(2,4- (CH3)2C6H3O)2PS2}2Fe{NC5H4(C2H5)-4}2] is synthesized and characterized by elemental analysis, magnetic moment, IR spectroscopy and single crystal X-ray analysis. Complex crystallizes in the monoclinic sp. gr. P21/n, Z = 2. Crystal structure consists of mononuclear units with Fe(II) ion chelated by four S atoms of the two diphenyldithiophosphate ligands in bidentate manner. N atoms from two 4-ethylpyridine ligands are axially coordinated to the Fe(II) atom leading to an octahedral geometry.

引用

页码：810 / 814

页数：4

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