Synthesis, characterization and single crystal x-ray analysis of a complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine

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作者：
Sandeep Kumar
Savit Andotra
Mandeep Kaur
Vivek K. Gupta
Rajni Kant
Sushil K. Pandey
机构：
[1] University of Jammu,Department of Chemistry
[2] Department of Physics and Electronics,X
[3] University of Jammu,ray Crystallographic Laboratory
来源：
Crystallography Reports | 2016年 / 61卷
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摘要：
Complex of iron(II) bis(2,4-dimethylphenyl)dithiophosphate with 4-ethylpyridine [{(2,4- (CH3)2C6H3O)2PS2}2Fe{NC5H4(C2H5)-4}2] is synthesized and characterized by elemental analysis, magnetic moment, IR spectroscopy and single crystal X-ray analysis. Complex crystallizes in the monoclinic sp. gr. P21/n, Z = 2. Crystal structure consists of mononuclear units with Fe(II) ion chelated by four S atoms of the two diphenyldithiophosphate ligands in bidentate manner. N atoms from two 4-ethylpyridine ligands are axially coordinated to the Fe(II) atom leading to an octahedral geometry.
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页码：810 / 814
页数：4
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