Hierarchical porous carbon derived from acai seed biowaste for supercapacitor electrode materials

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作者
Luiz K. C. de Souza
João Carlos Martins
Diogo Padilha Oliveira
Carlos Sergio Ferreira
Alexandre A. S. Gonçalves
Rayanne O. Araujo
Jamal da Silva Chaar
Maria J. F. Costa
David V. Sampaio
Raimundo R. Passos
Leandro A. Pocrifka
机构
[1] Federal University of Amazonas,Department of Chemistry
[2] Kent State University,Department of Chemistry and Biochemistry
[3] University of Sao Paulo,Department of Materials Engineering, School of Engineering of Sao Carlos
[4] Federal University of Sao Carlos,Department of Physics
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摘要
Creating energy storage devices from biomass waste has great scientific and industrial significance by providing an eco-friendly and sustainable alternative to reuse biowaste. This study demonstrates the production of high-performance supercapacitor electrodes using acai seed as a precursor for creating carbon materials. Porous carbons were synthesized by carbonization and subsequent KOH activation to generate microporosity then mesoporosity upon further activation. The materials displayed large specific surface areas and total pore volumes, with tunable pore structures depending on the degree of activation. The biomass-derived electrodes exhibited high specific capacitances of 346 F g−1 at 1 mA cm−2 and good electrochemical stability in which 88% of the initial capacitance was retained after 5000 charges/discharges cycles at 7 mA cm−2 in 1 M KOH electrolyte. These results place these materials among the best biomass-derived supercapacitors reported thus far. This study provides a great alternative for the management of the large-scale biowaste, acai seed.
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页码:12148 / 12157
页数:9
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