The Adsorption of CHClF2 on NaY5.6 Zeolite

被引：0
|
作者：
Mitsuhiro Yoshikawa
Toshihisa Yoshida
Mitsumasa Ishiwata
Toshio Hasegawa
Sentaro Ozawa
机构：
[1] Saitama University,Department of Physics
[2] Saitama University,Department of Science Education
[3] Saitama University,Department of Chemistry
[4] Akita University,Department of Materials
来源：
Adsorption | 2000年 / 6卷
关键词：
adsorption; zeolite; chlorodifluoromethane; adsorption structure; H and F NMR; chemicalshift; relaxation time; adsorbate mobility;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The adsorption of CHClF2 on NaY5.6 zeolite has been studied by measuring the H and F NMR of the adsorbed CHClF2, focusing in particular on the measurements of the chemical shift and longitudinal relaxation time, as well as the adsorption isotherm measurements. It is possible to determine the coordination structure of the CHClF2 adsorbed on NaY5.6 zeolite by measuring the adsorption amount dependence of the chemical shift. In addition, the motional activity of the adsorbed molecules in the super cage of the zeolite is discussed on the basis of observed longitudinal relaxation times for various adsorption amounts.
引用
收藏
页码：259 / 267
页数：8
相关论文
共 50 条
  • [21] SPECTROSCOPIC IDENTIFICATION OF CHCLF2 (F-22) IN THE LOWER STRATOSPHERE
    GOLDMAN, A
    MURCRAY, FJ
    BLATHERWICK, RD
    BONOMO, FS
    MURCRAY, FH
    MURCRAY, DG
    GEOPHYSICAL RESEARCH LETTERS, 1981, 8 (09) : 1012 - 1014
  • [22] Completing the picture in the rovibrational analysis of chlorodifluoromethane (CHClF2):: ν3 and ν8
    Thompson, CD
    Robertson, EG
    McNaughton, D
    MOLECULAR PHYSICS, 2004, 102 (14-15) : 1687 - 1695
  • [23] ADSORPTION OF C-60 IN ZEOLITE NAY
    JEON, IC
    HONG, SB
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1993, 14 (03) : 305 - 307
  • [24] Reactions of aliphatic fluoro-alcohols with CHClF2 at atmospheric pressure
    Mizukado, J
    Matsukawa, Y
    Quan, HD
    Tamura, M
    Sekiya, A
    JOURNAL OF FLUORINE CHEMISTRY, 2006, 127 (03) : 400 - 404
  • [25] Isotope-selective IR multiphoton dissociation of CHClF2 in the presence of NO2
    M.M. Ivanenko
    H. Handreck
    J. Göthel
    W. Fuss
    K.-L. Kompa
    P. Hering
    Applied Physics B, 1997, 65 : 577 - 582
  • [26] Isotope-selective IR multiphoton dissociation of CHClF2 in the presence of NO2
    Ivanenko, MM
    Handreck, H
    Gothel, J
    Fuss, W
    Kompa, KL
    Hering, P
    APPLIED PHYSICS B-LASERS AND OPTICS, 1997, 65 (4-5): : 577 - 582
  • [27] DETERMINATION OF ENERGY OF ACTIVATION OF THE CHCLF2 DECOMPOSITION IN HOMOGENEOUS PULSE LAZER PYROLYSIS
    MORDKOVICH, NY
    TVERITINOVA, EA
    NUGAEV, TBK
    TIMOFEEV, VV
    ZHITNEV, YN
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1990, 31 (04): : 337 - 340
  • [28] Pathways for the release of atomic chlorine from CHClF2 fragmentation by electron impact
    Sigaud, L.
    Ferreira, Natalia
    Coutinho, L. H.
    de Jesus, V. L. B.
    Montenegro, E. C.
    JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2012, 45 (21)
  • [29] IR MULTIPHOTON ABSORPTION AND ISOTOPICALLY SELECTIVE DISSOCIATION OF CHCLF2 IN A HERRIOTT MULTIPASS CELL
    FUSS, W
    GOTHEL, J
    IVANENKO, MM
    KOMPA, KL
    SCHMID, WE
    WITTE, K
    ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1994, 29 (04): : 291 - 298
  • [30] The rotational spectrum and nuclear quadrupole coupling of (CHClF2)-Cl-35
    Blanco, S
    Lesarri, A
    Lopez, JC
    Alonso, JL
    Guarnieri, A
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1996, 51 (1-2): : 129 - 132
12345