Synthesis and characterization of layered perovskite oxides (La, Sr)n + 1(Ti, Cr)nO3n + 1 (n = 1, 2)

被引：0
|
作者：
Sushma Sharma
Arun Mahajan
Suram Singh
Rajinder Singh
Devinder Singh
机构：
[1] University of Jammu,Department of Chemistry
来源：
Ionics | 2013年 / 19卷
关键词：
Layered perovskite oxides; XRD; Electrical properties; Magnetic properties;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
We report here the synthesis of layered perovskite oxides of the composition La0.5Sr1.5Ti0.5Cr0.5O4 and LaSr2TiCrO7 by conventional solid-state reaction method. Results of XRD analysis show that the phases crystallize with tetragonal unit cell in the space group I4/mmm. Both phases behave as insulators and the linearity of log ρ versus T−1/4 plot in the temperature range 150–350 K suggests that the electronic conduction occurs by Mott’s variable range hopping mechanism. The antiferromagnetic interactions observed for the samples arise from Cr3+–O–Cr3+ superexchange interaction.
引用
收藏
页码：505 / 509
页数：4
相关论文
共 50 条
  • [31] Photoluminescence of praseodymium-doped Srn+1Ti nO3n+1 (n = 1, 2, ∞)
    Inaguma, Yoshiyuki
    Nagasawa, Daisuke
    Katsumata, Tetsuhiro
    Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, 2005, 44 (1 B): : 761 - 764
  • [32] Effects of dimensionality on the electronic structure of Ruddlesden-Popper chromates Sr n+1 Cr n O 3 n+1
    Doyle, Spencer
    Takana, Lerato
    Anderson, Margaret A.
    Segedin, Dan Ferenc
    El-Sherif, Hesham
    Brooks, Charles M.
    Wang, Xiaoping
    Shafer, Padraic
    N'Diaye, Alpha T.
    El Baggari, Ismail
    Ratcliff, William D.
    Cano, Andres
    Meier, Quintin N.
    Mundy, Julia A.
    PHYSICAL REVIEW MATERIALS, 2024, 8 (07):
  • [33] Synthesis, characterization and dehydration study of H2A0.5nBnO3n+1•xH2O (n=2 and 3, A = Ca, Sr and B=Nb, Ta) compounds obtained by ion-exchange from the layered Li2A0.5nBnO3n+1 perovskite materials
    Bhuvanesh, NSP
    Crosnier-Lopez, MP
    Duroy, H
    Fourquet, JL
    JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (07) : 1685 - 1692
  • [34] STUDIES ON SYNTHESIS, CHARACTERIZATION AND CATALYTIC PROPERTIES OF LAN+1NINO3N+1 MIXED OXIDES
    CHENG, TX
    YANG, XG
    WU, Y
    ACTA CHIMICA SINICA, 1995, 53 (08) : 781 - 788
  • [35] Synthesis of N1,N1,N3,N3-tetrasubstituted diethylenetriamines
    D. Q. Hoang
    E. Ya. Borisova
    N. Yu. Borisova
    A. V. Krylov
    V. K. Lesnikov
    Russian Chemical Bulletin, 2018, 67 : 840 - 843
  • [36] Residue-to-Binary converters for the seven moduli set {2n-5-1, 2n-3-1, 2n-2+1, 2n-1-1, 2n-1+1, 2n, 2n+1} for n even
    Latha, M. V. N. Madhavi
    Rachh, Rashmi Ramesh
    Mohan, P. V. Ananda
    2019 IEEE ASIA PACIFIC CONFERENCE ON POSTGRADUATE RESEARCH IN MICROELECTRONICS AND ELECTRONICS (PRIMEASIA 2019): INNOVATIVE CAS TOWARDS SUSTAINABLE ENERGY AND TECHNOLOGY DISRUPTION, 2019, : 37 - 40
  • [37] High Speed Reverse Converter for the Five Moduli Set {2(n), 2(n)-1, 2(n)+1, 2(n)-3, 2(n-1)-1}
    Esmaeildoust, Mohammad
    Kaabi, Amer
    JOURNAL OF MATHEMATICS AND COMPUTER SCIENCE-JMCS, 2014, 9 (04): : 438 - 450
  • [38] Synthesis, characterization, and electrocatalytic properties of La0.9Sr0.1Cr1-x Co x O3 perovskite oxides
    Makhloufi, Sofiane
    Omari, Elies
    Omari, Mahmoud
    JOURNAL OF THE AUSTRALIAN CERAMIC SOCIETY, 2019, 55 (01) : 1 - 10
  • [39] Layered Perovskites BaLnnInnO3n+1 (n=1, 2) for Electrochemical Applications: A Mini Review
    Tarasova, Nataliia
    MEMBRANES, 2023, 13 (01)
  • [40] SYNTHESIS AND INTERCALATION REACTIONS OF K[(CA,SR)N-1NB3TIN-3O3N+1]
    RAM, RAM
    CLEARFIELD, A
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 200 : 309 - INOR
12345