Nature of Contamination and Preparation of Pure Precipitates of Rh(III) and Ir(III) Ammonium Sodium Hexanitrites

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作者
S. V. Korenev
A. B. Venediktov
V. A. Nadolinnyi
A. V. Belyaev
机构
[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Division
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Sodium; Copper; Ammonium; Purification; Crystalline Phasis;
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摘要
Various spectroscopic methods and X-ray phase analysis were applied to study the distribution of copper(II) and lead(II) between the solution and the precipitate of (NH4)2Na[Rh(NO2)6]. Promising methods are proposed for fine purification of ammonium sodium hexanitrites of rhodium(III) and iridium(III) to remove contaminants, irrespective of the mechanism of their ingress into crystalline phases.
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页码:7 / 11
页数:4
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