Synthesis and physico-chemical properties of 2,7,12,17-tetraphenylporphycene and its metal complexes

被引：0
|
作者：
D. B. Berezin
A. E. Talanova
O. V. Shukhto
S. S. Guseinov
M. A. Krest’yaninov
D. V. Petrova
A. S. Semeikin
机构：
[1] Ivanovo State University of Chemistry and Technology,Research Institute of Macroheterocyclic Compounds
[2] Russian Academy of Sciences,Krestov Institute of Solutions Chemistry
来源：
Russian Journal of General Chemistry | 2015年 / 85卷
关键词：
porphyrinoid; porphycene; synthesis; N-basicity; tautomerism; thermal stability; metal complex; dissociation;
D O I：
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中图分类号：
学科分类号：
摘要：
Porphycene, β-phenyl-substituted analog of tetraphenylporphyrin, and its complexes with Cu(II) and Zn(II) have been prepared. Spectral parameters of the porphycene, its acid-base properties and thermal stability in the solid phase as well as its complexes stability towards dissociation in acidic medium have been studied by means of electronic absorption and NMR spectrometry, mass spectroscopy, thermogravimetry, and quantum chemistry simulation.
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页码：1876 / 1884
页数：8
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