Synthesis and physico-chemical properties of 2,7,12,17-tetraphenylporphycene and its metal complexes

被引：5

作者：

Berezin, D. B. ^{[1
]}

Talanova, A. E. ^{[1
]}

Shukhto, O. V. ^{[1
]}

Guseinov, S. S. ^{[2
]}

Krest'yaninov, M. A. ^{[2
]}

Petrova, D. V. ^{[1
]}

Semeikin, A. S. ^{[1
]}

机构：

[1] Ivanovo State Univ Chem & Technol, Res Inst Macroheterocycl Cpds, Ivanovo 153000, Russia

[2] Russian Acad Sci, Krestov Inst Solut Chem, Ivanovo, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 08期

关键词：

porphyrinoid; porphycene; synthesis; N-basicity; tautomerism; thermal stability; metal complex; dissociation; PORPHYCENE; ETIOPORPHYCENE; STABILITY; BONDS; ZINC;

D O I：

10.1134/S1070363215080150

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Porphycene, beta-phenyl-substituted analog of tetraphenylporphyrin, and its complexes with Cu(II) and Zn(II) have been prepared. Spectral parameters of the porphycene, its acid-base properties and thermal stability in the solid phase as well as its complexes stability towards dissociation in acidic medium have been studied by means of electronic absorption and NMR spectrometry, mass spectroscopy, thermogravimetry, and quantum chemistry simulation.

引用

页码：1876 / 1884

页数：9

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