Chemo- and regioselective nitration of geranylacetone by NaNO2/AcOH. Synthesis of 6,10-dimethyl-9-methyleneundec-5E-en-2-one

被引：0

作者：

A. V. Stepanov

V. V. Veselovsky

机构：

[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry

来源：

Russian Chemical Bulletin | 1999年 / 48卷

关键词：

linear isoprenoid; geranylacetone; nitration; nitro derivative; Nef reaction; 6,10-dimethyl-9-methyleneundec-5; -en-2-one; essential oil component;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Treatment of geranylacetone with NaNO2 in AcOH affords 6,10-dimethyl-9-nitroundeca-5E,10-dien-2-one as the major product. This product was used to synthesize 6,10-dimethyl-9-methyleneundec-5E-en-2-one, a component of the essential oil from the roots of theSaussurea lappa plant.

引用

页码：1287 / 1290

页数：3

共 50 条

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