Chemo- and regioselective nitration of geranylacetone by NaNO2/AcOH.: Synthesis of 6,10-dimethyl-9-methyleneundec-5E-en-2-one

被引：1

作者：

Stepanov, AV ^{[1
]}

Veselovsky, VV ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 07期

关键词：

linear isoprenoid; geranylacetone; nitration; nitro derivative; Nef reaction; 6,10-dimethyl-9-methyleneundec-5E-en-2-one essential oil component;

D O I：

10.1007/BF02495291

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of geranylacetone with NaNO2 in AcOH affords 6,10-dimethyl-9-nitroundeca-5E,10-dien-2-one as the major product. This product was used to synthesize 6,10-dimethyl-9-methyleneundec-5E-en-2-one, a component of the essential oil from the roots of the Saussurea lappa plant.

引用

页码：1287 / 1290

页数：4

共 50 条

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A. V. Stepanov
V. V. Veselovsky
[J]. Russian Chemical Bulletin, 1999, 48 : 1287 - 1290
[2] TOTAL AND STEREOSELECTIVE SYNTHESIS OF (E)-6,10-DIMETHYL-9-METHYLIDENEUNDEC-5-EN-2-ONE, A CONSTITUENT OF COSTUS ROOT OIL
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