A Zn(II) ion-selective electrode based on chalcogenide As2Se3–Sb2Se3–ZnSe and GeSe2–ZnSe–ZnTe glasses

被引:0
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作者
S.V. Boycheva
V.S. Vassilev
Z.G. Ivanova
机构
[1] University of Chemical Technology and Metallurgy,Department of Semiconductors
[2] Bulgarian Academy of Sciences,Institute of Solid State Physics
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关键词
chalcogenide glasses; ion-selective electrodes; membranes;
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摘要
Zn(II) ion-selective electrodes with chalcogenide glassy As2Se3–Sb2Se3–ZnSe and GeSe2–ZnSe–ZnTe membranes were developed. Basic analytical characteristics such as stability, linearity, slope of the electrode function, limits of detection, effect of pH on the electrode potential and response time were studied with varying glass compositions. A structural mechanism for explanation of the dependencies obtained is suggested.
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页码:281 / 285
页数:4
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