The formation of Pt-Ru alloy nanoparticles in a carbon matrix under IR pyrolysis conditions

被引：0
|
作者：
M. N. Efimov
E. L. Dzidziguri
E. N. Sidorova
K. O. Chuprunov
L. M. Zemtsov
G. P. Karpacheva
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
[2] Moscow Institute of Steel and Alloys,undefined
来源：
Russian Journal of Physical Chemistry A, Focus on Chemistry | 2008年 / 82卷
关键词：
Metallic Nanoparticles; Carbon Matrix; DMFA; Alloy NANOPARTICLES; Coherent Scatter Region;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Nanosized Pt-Ru alloy and Pt13Ru27 intermetallic compound particles dispersed in a carbon matrix were obtained for the first time directly during the preparation of the composite. The alloying of the Pt and Ru particles occurred at IR pyrolysis intensities corresponding to temperatures above 700°C over the whole homogeneity range of solid solutions based on platinum. Metallic nanoparticles were round-shaped (the mean size 6–8 nm) and had a narrow particle-size distribution.
引用
收藏
页码：1175 / 1178
页数：3
相关论文
共 50 条
  • [21] Ethanol electro-oxidation on carbon-supported Pt-Ru, Pt-Rh and Pt-Ru-Rh nanoparticles
    Lima, F. H. B.
    Gonzalez, E. R.
    ELECTROCHIMICA ACTA, 2008, 53 (06) : 2963 - 2971
  • [22] On the reaction pathway for methanol and carbon monoxide electrooxidation on Pt-Sn alloy versus Pt-Ru alloy surfaces
    Univ of California, Berkeley, United States
    Electrochim Acta, 16 (2587-2593):
  • [23] Preparation and characterization of aqueous colloids of Pt-Ru nanoparticles
    Shimazaki, Y
    Kobayashi, Y
    Yamada, S
    Miwa, T
    Konno, M
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 292 (01) : 122 - 126
  • [24] Effect of Reduction Temperature on the Preparation and Characterization of Pt-Ru Nanoparticles on Multiwalled Carbon Nanotubes
    Chetty, Raghuram
    Xia, Wei
    Kundu, Shankhamala
    Bron, Michael
    Reinecke, Thomas
    Schuhmann, Wolfgang
    Muhler, Martin
    LANGMUIR, 2009, 25 (06) : 3853 - 3860
  • [25] Electrochemical impedance analysis of methanol oxidation on carbon nanotube-supported Pt and Pt-Ru nanoparticles
    Ma, Bo
    Bai, Jincheng
    Dong, Lifeng
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2013, 17 (11) : 2783 - 2788
  • [26] Carbon support effects on bimetallic Pt-Ru nanoparticles formed from molecular precursors
    Hills, CW
    Nashner, MS
    Frenkel, AI
    Shapley, JR
    Nuzzo, RG
    LANGMUIR, 1999, 15 (03) : 690 - 700
  • [27] Electrochemical impedance analysis of methanol oxidation on carbon nanotube-supported Pt and Pt-Ru nanoparticles
    Bo Ma
    Jincheng Bai
    Lifeng Dong
    Journal of Solid State Electrochemistry, 2013, 17 : 2783 - 2788
  • [28] Electroactivity of high performance unsupported Pt-Ru nanoparticles in the presence of hydrogen and carbon monoxide
    Laboratori d'Electroquímica Dels Materials i Del Medi Ambient, Departament de Química Física, Universitat de Barcelona, Martí i Franqus 1-11, 08028 Barcelona, Spain
    Int J Hydrogen Energy, 1600, 20 (11591-11600):
  • [29] Structure and composition of single Pt-Ru electrocatalyst nanoparticles supported on multiwall carbon nanotubes
    Paraguay-Delgado, Francisco
    Malac, Marek
    Alonso-Nunez, Gabriel
    MATERIALS RESEARCH EXPRESS, 2014, 1 (04):
  • [30] Electroactivity of high performance unsupported Pt-Ru nanoparticles in the presence of hydrogen and carbon monoxide
    Velazquez-Palenzuela, Amado
    Cabot, Pere-Lluis
    Centellas, Francesc
    Antonio Garrido, Jose
    Arias, Conchita
    Maria Rodriguez, Rosa
    Brillas, Enric
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (20) : 11591 - 11600
12345