β-Elimination in 1,1,1-Trichloro-2,2-bis(4-nitrophenyl)ethane by the Action of Sodium Nitrite in Dipolar Aprotic Solvents

被引：0
|
作者：
E. A. Guzov
V. N. Kazin
A. A. Zhukova
机构：
[1] Demidov Yaroslavl State University,
来源：
Russian Journal of General Chemistry | 2018年 / 88卷
关键词：
1,1,1-trichloro-2,2-bis(4-nitrophenyl)ethane; nitrite ion; quantum chemical simulation; solvation;
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中图分类号：
学科分类号：
摘要：
The kinetics of dehydrochlorination of 1,1,1-trichloro-2,2-bis(4-nitrophenyl)ethane with sodium nitrite in dipolar aprotic solvents have been studied. Quantum chemical simulation of the process has been performed, and its thermodynamic parameters have been determined. The effects of dissociation and solvation on the rate constant have been considered. The reaction mechanism has been identified as E2H.
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页码：2044 / 2049
页数：5
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