(R)-4-menthenone in reactions of 1,4-conjugate and 1,3-dipolar addition

被引：0
|
作者：
G. Yu. Ishmuratov
E. R. Latypova
P. Ya. Kharisov
R. R. Muslukhov
A. A. Bannova
R. F. Talipov
G. A. Tolstikov
机构：
[1] Russian Academy of Sciences,Institute of Organic Chemistry, Ufa Scientific Center
[2] Bashkirian State University,undefined
来源：
Russian Journal of Organic Chemistry | 2008年 / 44卷
关键词：
CuBr; Ethyl Acetoacetate; Michael Reaction; Organometallic Reagent; EtMgBr;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
(R)-4-Menthenone compared with common cyclic enones exhibits considerably lower reactivity in 1,4-conjugate addition of organometallic reagents, is inert in Michael reactions and pyrazoline formation evidently due both to the distorted polarization in the enone system and to steric hindrances from the α-isopropyl group in the cyclohexene ring.
引用
收藏
页码：652 / 656
页数：4
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