Selective reduction of nitroarenes to N-arylhydroxylamines by use of Zn in a CO2–H2O system, promoted by ultrasound

被引：0
|
作者：
Shijuan Liu
Yanhua Wang
Xun Yang
Jingyang Jiang
机构：
[1] Jilin Normal University,College of Chemistry
[2] Dalian University of Technology,State Key Laboratory of Fine Chemicals, Faculty of Chemical Environmental and Biological Science and Technology
来源：
Research on Chemical Intermediates | 2012年 / 38卷
关键词：
Nitroarenes; Reduction; Zn; CO; –H; O; Ultrasound; -Arylhydroxylamines;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The promoting effect of ultrasound on the selective reduction of nitroarenes to N-arylhydroxylamines by use of Zn in an environmentally benign CO2–H2O system has been demonstrated. The yield of N-phenylhydroxylamine reaches 95 % when the reaction is carried out with a Zn-to-nitrobenzene molar ratio of 2.2 under ultrasound (40 kHz) at 25 °C and normal pressure of CO2 for 60 min. Application of ultrasound to the reaction has the advantages of higher yield of N-arylhydroxylamines, shorter reaction time, and consumption of less Zn.
引用
收藏
页码：2471 / 2478
页数：7
相关论文
共 50 条
  • [21] Behavior of Chlorine in HCl/H2O/O2/CO2/N2 Reaction System
    Cheng, Yi
    Sato, Atsushi
    Ninomiya, Yoshihiko
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2008, 41 (06) : 519 - 524
  • [22] Facile synthesis of Mo-doped TiO2 for selective photocatalytic CO2 reduction to methane: Promoted H2O dissociation by Mo doping
    Feng, Shuaijun
    Zhao, Jie
    Bai, Yujie
    Liang, Xinxin
    Wang, Ting
    Wang, Chuanyi
    JOURNAL OF CO2 UTILIZATION, 2020, 38 : 1 - 9
  • [23] The CO2 absorption and desorption performance of the triethylenetetramine + N,N-diethylethanolamine + H2O system
    Yaoyao Li
    Changjun Liu
    Richard Parnas
    Yingying Liu
    Bin Liang
    Houfang Lu
    ChineseJournalofChemicalEngineering, 2018, 26 (11) : 2351 - 2360
  • [24] Mechanism of Zn Particle Oxidation by H2O and CO2 in the Presence of ZnO
    Weibel, David
    Jovanovic, Zoran R.
    Galvez, Elena
    Steinfeld, Aldo
    CHEMISTRY OF MATERIALS, 2014, 26 (22) : 6486 - 6495
  • [25] Parallel tempering Monte Carlo simulations of (H2O)N, (H2O)N+, and (CO2)N clusters.
    Jordan, KD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U509 - U509
  • [26] Environmentally benign and selective reduction of nitroarenes with Fe in pressurized CO2-H2O medium
    Gao, Ge
    Tao, Yuan
    Jiang, Jingyang
    GREEN CHEMISTRY, 2008, 10 (04) : 439 - 441
  • [27] Electrocatalytic Reduction of CO2 and H2O with Zn(II) Complexes Through Metal-Ligand Cooperation
    Norouziyanlakvan, Somayeh
    Berro, Patrick
    Rao, Gyandshwar Kumar
    Gabidullin, Bulat
    Richeson, Darrin
    CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (21)
  • [28] Electron transfer reactions of nitromethane, acetaldehyde and benzaldehyde with (H2O)n-, CO2•-(H2O)n, and O2-(H2O)n, n < 110, in the gas phase
    Akhgarnusch, Amou
    Beyer, Martin K.
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2014, 365 : 295 - 300
  • [29] Effects of CO2 on H2O band profiles and band strengths in mixed H2O:CO2 ices
    Oberg, K. I.
    Fraser, H. J.
    Boogert, A. C. A.
    Bisschop, S. E.
    Fuchs, G. W.
    van Dishoeck, E. F.
    Linnartz, H.
    ASTRONOMY & ASTROPHYSICS, 2007, 462 (03) : 1187 - 1198
  • [30] Effects of CO2 on H2O band profiles and band strengths in mixed H2O:CO2 ices
    Öberg, K.I.
    Fraser, H.J.
    Boogert, A.C.A.
    Bisschop, S.E.
    Fuchs, G.W.
    Van Dishoeck, E.F.
    Linnartz, H.
    Astronomy and Astrophysics, 1600, 462 (03): : 1187 - 1198
12345